[6,6]-Phenyl C61 butyric acid methyl ester (684430) – Sigma-Aldrich
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Synonyms
1-[3-(Methoxycarbonyl)propyl]-1-phenyl-[6.6]C61, 3′H-Cyclopropa[1,9] [5,6]fullerene-C60-Ih-3′-butanoic acid 3′-phenyl methyl ester, PCBM, [60]PCBM
General Description
[6,6]-Phenyl C61 butyric acid methyl ester ([60]PCBM) is a methanofullerene that has a better diffusion in organic molecules than fullerenes(C60). It has high electron mobility which allows it to be used as an electron acceptor in major electrochemical applications.
Applications
Soluble n-channel organic semiconductor. For use as an n-type layer in plastic electronics, especially bulk heterojunction OFETs and photovoltaic cells (PVs).
[60]PCBM is an n-type semi-conductor widely used as an a electron transport material with low cost and high surface area in different energy based applications like organic photovoltaics (OPVs), perovskite solar cells (PSCs), organic field effect transistors (OFETs) and photodetectors
[6,6]-Phenyl C61 butyric acid methyl ester (684449) – Sigma-Aldrich
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Synonyms
1-[3-(Methoxycarbonyl)propyl]-1-phenyl-[6.6]C61, 3′H-Cyclopropa[1,9] [5,6]fullerene-C60-Ih-3′-butanoic acid 3′-phenyl methyl ester, PCBM, [60]PCBM
General Description
(6,6)-Phenyl C61 butyric acid methyl ester ((60) PCBM) is a methanofullerene that has a better diffusion in organic molecules than fullerenes (C60). It has a high electron mobility which allows it to be used as an electron acceptor in major electrochemical applications.
Applications
(60)PCBM is an n-type semi-conductor widely used as an a electron transport material with low cost and high surface area in different energy based applications like organic photovoltaics, perovskite solar cells, field effect transistors and photodetectors.
Soluble n-channel organic semiconductor. For use as an n-type layer in plastic electronics, especially bulk heterojunction OFETs and photovoltaic cells (PVs).
[60]PCBM is an n-type semi-conductor with low cost and high surface area. It is widely used as an electron transport material in various energy-based applications like organic photovoltaics, perovskite solar cells, field effect transistors, and photodetectors.
[6,6]-Phenyl C61 butyric acid methyl ester (684457) – Sigma-Aldrich
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Synonyms
1-[3-(Methoxycarbonyl)propyl]-1-phenyl-[6.6]C61, 3′H-Cyclopropa[1,9] [5,6]fullerene-C60-Ih-3′-butanoic acid 3′-phenyl methyl ester, PCBM, [60]PCBM
General Description
[6,6]-Phenyl C61 butyric acid methyl ester ([60]PCBM) is a methanofullerene that has a better solubility in organic solvents than fullerenes(C60). It has high electron mobility, which enables its function as an electron acceptor in electrochemical applications.
Applications
Soluble n-channel organic semiconductor. For use as an n-type layer in plastic electronics, especially bulk heterojunction OFETs and photovoltaic cells (PVs).
[60]PCBM is an n-type semi-conductor widely used as an electron transport material with low cost and high surface area in different energy based applications like organic photovoltaics (OPVs), perovskite solar cells (PSCs), field effect transistors (FETs) and photodetectors
1,2-Butanediol purum, ≥98.0% (GC) (Sigma)
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Description
Grade: Purum
Assay: ≥98.0% (GC)
Synonym: 1,2-Butylene glycol
1,2-Butanediol has been used:
2,2-Diphenyl-1-picrylhydrazyl – Sigma – Aldrich
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Description
CAS Number: 1898-66-4
Molecular weight : 394.32 g/mol
Empirical formula : C18H12N5O6
Synonyms : 1,1-Diphenyl-2-picrylhydrazyl radical, 2,2-Diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl, DPPH
2,2-diphenyl-1-picrylhydrazyl is a type of free radical that can accept hydrogen from antioxidants, making it a useful tool in the DPPH assay for evaluating the antioxidant activity of various natural samples, including wine, fruits, and herbal tea.
3-Chloroperbenzoic acid, ≤77% (Sigma-Aldrich)
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Description:
CAS number: 937-14-4
Chemical Formula: ClC6H4CO3H
Molar Mass: 172.57 g/mol
Synonyms: 3-Chloroperoxybenzoic acid, meta-Chloroperbenzoic acid, MCPBA
General description
3-Chloroperbenzoic acid is a strong oxidizing agent mainly used for the epoxidation of alkenes and also in the Baeyer-Villiger oxidation of ketones to esters.
Application
3-Chloroperbenzoic acid has been used in the oxidation of N–p-tolylsulfinyl-(E)-1-phenylethylideneimine to N–p-tolylsulfonyl (E)-1-phenylethylideneimine using dichloromethane as a solvent. It has also been used in the preparation of mono- and di-epoxy-functionalized poly(3-hydroxybutyrate)-based reactive polymers. MCPBA is also an effective oxidizing agent for the conversion of α-amide substituted polyesters to their corresponding polysulfones with tunable thermal properties.
Effective oxidant for epoxidizing di-, tri-, and tetra-substituted olefins.
4-Nitrophenyl butyrate, ≥98% (Sigma-Aldrich)
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Description
CAS number: 2635-84-9
Chemical Formula: C10H11NO4
Molar Mass: 209.20 g/mol
Synonyms: p-Nitrophenyl butyrate, Butyric acid 4-nitrophenyl ester
General description
4-Nitrophenyl butyrate is a substrate for esterase, and lipase enzyme. Hydrolysis of 4-nitrophenyl butyrate by these enzymes releases the chromophore, 4-nitrophenolate which is spectrophotometrically analysed at 415 nm.
Application
4-nitrophenyl butyrate has been used:
• as a substrate for esterase activity in monocyte-derived macrophage cell line in response to polyethylene
• as a substrate for mycobacterial phospholipase A and mycobacterial cutinase activity
• as a substrate to determine the effect of buffers and solvents on human carboxylesterase
Benzene Anhydrous, 99.8% – Sigma-Aldrich
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Description
CAS Number: 71-43-2
Empirical Formula: C6H6
Molecular Weight: 78.11
Synonyms: –
Assay: 99.8%
Benzene is a six-membered aromatic compound that can undergo ionization induced by superhalogens, according to ab initio calculations. This compound is a frequently used industrial solvent but is also considered an air pollutant and a powerful carcinogen.
Benzene may be used in the formation of phenyl acetate by aerobic oxidation using Pd catalyst and acetic acid as solvent, formation of phenol by hydroxylation in the presence of mesoporous carbon nitride supported on vanadium catalyst and as a solvent to prepare nanoparticles of gallium nitride (GaN) by reacting Li3N and GaCl3 at 280°C.
BT-CIC – Sigma-Aldrich
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Synonyms
4,4,10,10-tetrakis(4-hexylphenyl)-5,11-(2-ethylhexyloxy)-4,10-dihydrodithienyl[1,2-b:4,5b′ ]benzodithiophene-2,8-diyl)bis(2-(3-oxo-2,3-dihydroinden-5,6-dichloro-1-ylidene)malononitrile), NFA147, PCE147
CAS No
2197167-51-2
General Description
BT-CIC is a highly efficient, ultra-narrow bandgap, NIR absorbing, non-fullerene acceptor, designed to use in high performance organic photovoltaic devices.
A recently reported tandem cell, employing BT-CIC as the non-fullerene acceptor and PCE-10 as donor for the back cell showed an PCE of 15%.
Device performance:
Tandem [Front] (170 nm DTDCPB:C70 + ARC) [Back]PCE-10:BTCIC (1:1.5, 75 nm)
Jsc=13.3 ± 0.3 mA/cm2
Voc=1.59 ± 0.01 V
FF=0.71± 0.01
PCE=15.0% ± 0.3%
ARC: an antireflection coating
Cesium iodide, 99.999% trace metals basis – Sigma-Aldrich
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Synonyms
Caesium iodide, Caesium monoiodide
Applications
Cesium iodide can be used as precursor to synthesize lead-free perovskite material, Cs2NaBiI6 (CNBI). The CNBI is highly stable and finds application in the field of solar cells, LEDs, and lasers.
It can be used to prepare brightest red emitting Cs2HfI6 scintillator which is applicable in high resolution gamma spectroscopy.
It can also be used tosynthesize Cesium based nanocrystals for the detection of ionizingradiations.
Features & Benefits
- High quantum efficiency
- High stability to ambient air and gas environment
Frequently used in devices such as phosphor screens for medical imaging, scintillators, calorimeters and a variety of particle detectors.
| CAS Number |
7789-17-5 |
| Empirical Formula |
CsI |
| Molecular Weight |
259.81 |
| Form |
Solid |
| Assay |
99.999% trace metals basis |
| Impurities |
≤15.0 ppm Trace Metal Analysis |
| Application(s) |
solar cells, LEDs, and lasers |
Cesium Iodide, AnhydroBeads™, 99.999% trace metals basis (Perovskite grade) – Sigma Aldrich
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Synonyms
Cesium monoiodide
General Description
Cesium iodide anhydrous can be used as a precursor or component in the synthesis of the perovskite absorber layer in perovskite solar cells. By introducing cesium iodide into the perovskite composition, the bandgap of the material can be tuned to better match the solar spectrum, optimizing the light absorption and energy conversion efficiency of the solar cell.
Cesium iodide finds application in synthesis of perovksites based photovoltaic materials. Our perovskite grade CsI can readily be dissolved in 1:1 vol DMF/DMSO to yield 1M solution.
Features & Benefits
Frequently used in devices such as phosphor screens for medical imaging, scintillators, calorimeters and a variety of particle detectors.
Packing
Packaged in ampules
Legal Information
AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
| CAS Number |
7789-17-5 |
| Empirical Formula |
CsI |
| Molecular Weight |
259.81 |
| Product line |
AnhydroBeads™ |
| Assay |
99.999% trace metals basis |
| Form |
crystals |
| Particle size |
~10 mesh |
COi8DFIC – Sigma-Aldrich
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Synonyms
2,2′-[[4,4,11,11-tetrakis(4-hexylphenyl)-4,11-dihydrothieno[2′,3′:4,5]thieno[2,3-d]thieno[2′′′′,3′′′′:4′′′,5′′′]thieno[2′′′,3′′′:4′′,5′′]pyrano[2′′,3′′:4′,5′]thieno[2′,3′:4,5]thieno[3,2-b]pyran-2,9-diyl]bis[methylidyne(5,6-difluoro, NFA146, O6T-4F, PCE146
CAS No
2184266-44-0
General Description
COi8DFIC or O6T-4F is a highly efficient, n-type, low-bandgap nonfullerene acceptor with strong NIR absorption.
In a recent study, COi8DFIC or O6T-4F was selected in a Tandem cell by computer assited design and gave a record PCE of 17.3∃% for fabricated organic solar cells.
COi8DFIC or O6T-4F is frequently selected to blend with a narrow-bandgap donor material and another narrow bandgap acceptor material to fabricate ternary organic solar cells. The PTB7-Th:COi8DFIC:PC71BM ternary cells offered a PCE of 14.08%. By further adopting a post-annealing process, an outstanding PCE of 14.62% can be achieved. Furthermore, the device utilizing COi8DFIC exhibited a good thermal stability with PCEs over 13.5% in a wide temperature range (70–160 °C).
Application
COi8DFIC is primarily utilized as a non-fullerene acceptor in OPV devices. It exhibits a broad absorption spectrum, enabling it to absorb light across a wide range of wavelengths, including the visible and near-infrared regions. This property allows for efficient utilization of a broader range of solar radiation, enhancing the light-harvesting capability of the OPV device. COi8DFIC can be employed as the electron transport material in OFET devices.
COi8DFIC or O6T-4F is a highly efficient, n-type, low-bandgap nonfullerene acceptor with strong NIR absorption
In a recent study, COi8DFIC or O6T-4F was selected in a Tandem cell by computer assited design and gave a record PCE of 17.3% for fabricated organic solar cells.
Tandem Cell Device performance:
ITO/ZnO/PFN-Br/PBDB-T:F-M/M-PEDOT/ZnO/PTB7- Th:O6T-4F:PC71BM/MoO3/Ag
Voc=1.642 V
Jsc=14.35 mA/cm2
FF=73.7%
PCE=17.3%
COi8DFIC or O6T-4F is frequently selected to blend with a narrow-bandgap donor material and another narrow bandgap acceptor material to fabricate ternary organic solar cells. The PTB7-Th:COi8DFIC:PC71BM ternary cells offered a PCE of 14.08%. By further adopting a post-annealing process, an outstanding PCE of 14.62% can be achieved. Furthermore, the device utilizing COi8DFIC exhibited a good thermal stability with PCEs over 13.5% in a wide temperature range (70-160 °C).
Device structure:
ITO/ZnO/PTB7-Th:COi8DFIC:PC71BM/MoO3/Ag
Before annealing
Voc=0.702 V
Jsc=27.74 mA/cm2
FF=0.701
PCE=13.65%
After annealing at 80°C
Voc=0.727 V
Jsc=27.39 mA/cm2
FF=0.734
PCE=14.62%
COi8DFIC, an efficient non-fullerene acceptor material, has a strong near-infrared range (NIR) light absorption. It can be used as an n-type small molecule acceptor material for the fabrication of polymeric solar cells.
Corning® CoolCell™ FTS30 (Sigma-Aldrich)
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Description
CoolCelll FTS30 utilizes a solid state core and controlled microconvection technology to evenly draw in -80°C freezer air through a bottom base vent, uniformly disperse the cold air around each vial in the central chamber and then release the thermal load from the vials through a top vent choke. The inner vial module holds 30 cryogenic vials and can be removed in one step. Each vial achieves a uniform and reproducible -1°C/minute freezing profile and thermal profiles are highly reproducible. Due to the low thermal mass of the uniform-density cross-linked polyethylene foam container, freezing can be conducted without a rise in local freezer temperature, thereby protecting nearby samples.
Application :
-For 30 standard 1.0 mL to 2.0 mL cryogenic vials.
-Controlled micro-convection for uniform freezing of 30 vials.
-Removable vial tray for one-step transfer of samples into and out of freezing chamber.
Cycloheximide from microbial, ≥94% (TLC) (Sigma-Aldrich)
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Description
CAS number: 66-81-9
Chemical Formula: C15H23NO4
Molar Mass: 281.35 g/mol
Synonyms: 3-[2-(3,5-Dimethyl-2-oxocyclohexyl)-2-hydroxyethyl]glutarimide, Actidione, Naramycin A
Application
In yeast strains, cycloheximide has been used as a protein synthesis inhibitor in the cycloheximide chase experiment. It has been used to inhibit translation in mammalian cells and suppress fungal growth.
Biochem/physiol Actions
Cycloheximide (CHX) is an antibiotic produced by S. griseus. Its main biological activity is translation inhibition in eukaryotes resulting in cell growth arrest and cell death. CHX is widely used for selection of CHX-resistant strains of yeast and fungi, controlled inhibition of protein synthesis for detection of short-lived proteins and super-induction of protein expression, and apoptosis induction or facilitation of apoptosis induction by death receptors.
di-n-butylammonium methylammonium lead(II) heptaiodide – Sigma-Aldrich
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Synonyms
(BA)2(MA)Pb2I7, 2D perovskite, Bis(butylammonium) methylammonium heptaiododiplumbate
General Description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for “Energy efficiency”.
Applications
2D perovskites have been used as the active material in may applications such as light emmiting diodes,[1] phototransistors,[2] and solar cells.[3] Unlike 3D perovskites, these layered materials give higher moisture stability and longer device lifetimes.
Dimethyl Sulfoxide, ≥99.7% (Sigma-Aldrich)
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**This product has been discontinued, please contact us for more information.
Description
CAS number: 67-68-5
Chemical Formula: (CH3)2SO
Molar Mass: 78.13 g/mol
Sterility: Sterile-filtered
Synonyms: DMSO
Application
DMSO is a polar aprotic solvent used in chemical reactions, in polymerase chain reactions (PCR) and as a cryoprotectant vitrification agent for the preservation of cells, tissues and organs. DMSO is used in cell freezing media to protect cells from ice crystal-induced mechanical injury. It is used for frozen storage of primary, sub-cultured, and recombinant heteroploid and hybridoma cell lines; embryonic stem cells (ESC), and hematopoietic stem cells. DMSO is frequently used in the combinations with BSA or fetal bovine serum (FBS).
Other Notes
This product is a Hybri-Max product. It is hybridoma tested and is assessed for suitability in cell freezing. This product is sterile filtered (0.2 micron) and tested for endotoxin levels.
Dimethyl Sulfoxide, Anhydrous, ≥99.9% (Sigma-Aldrich)
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Description
CAS number: 67-68-5
Linear Formula: (CH3)2SO
Molecular Weight 78.13
Synonym: DMSO
General description
Dimethyl Sulfoxide (DMSO) is an apolar protic solvent that is generally used as a reaction medium and reagent in organic reactions.
Application
Dimethyl Sulfoxide may be used as an oxidant for the conversion of isonitriles into isocyanates. DMSO activated by oxalyl chloride can be used in the oxidation of long-chain alcohols to carbonyls.
Dimidium bromide, BioReagent, suitable for fluorescence, ~95% (AT), Sigma
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CAS number: 518-67-2
Chemical Formula: C20H18BrN3
Molar Mass: 380.28 g/mol
Synonyms: 3,8-Diamino-5-methyl-6-phenylphenanthridinium bromide, Trypadine
Application
Intercalating probe for nucleic acids. Suitable for fluorescence.
Dulbecco’s Modified Eagle’s Medium (DMEM), powder form
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Dulbecco′s Modified Eagle′s Medium (DMEM) is a modification of Basal Medium Eagle (BME) that contains four-fold concentrations of the amino acids and vitamins which suitable for cell culture. The original formulation contained 1000 mg/L of glucose and was used to culture embryonic mouse cells. Since then, it has been modified in several ways to support primary cultures of mouse and chicken cells, as well as a variety of normal and transformed cells. Each of these media offers a different combination of L-glutamine and sodium pyruvate. Refer to the table below and choose your prefered DMEM!
F-M – Sigma-Aldrich
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Synonyms
4,4,7,7,12,12-octyl-7,12-dihydro- bis[methylidyne(3-oxo-methyl-1H indene-2,1(3H)-diylidene)]]bis-4H-thieno[2″,3″:1′,2′]indeno[5′,6′:5,6]-s-indaceno[1,2-b]thiophene, FTIC-C8C8M
CAS No
2239303-91-2
General Description
Non-fullerene acceptors (NFAs) are currently a major focus of research in the development of bulk-heterojunction organic solar cells (OSCs). In contrast to the widely used fullerene acceptors (FAs), the optical properties and electronic energy levels of NFAs can be designed and readily tuned. NFA-based OSCs can also achieve greater thermal stability and photochemical stability, as well as longer device lifetimes, than their FA-based counterparts. Recent developments have led to a rapid increase in power conversion efficiencies for NFA OSCs, with values now exceeding 15% in a single junction cell, and >17% for a tandem cell, demonstrating the viability of using NFAs to replace FAs in next-generation high-performance OSCs.
Application
F-M is a non-fullerene acceptor that absorbs visible light, when used in a front cell paired with NIR absorbing rear cell, the resulted tandem organic solar cell gave a record energy conversion efficiency of 17.3%.[1]
Tandem Cell Device performance:
ITO/ZnO/PFN-Br/PBDB-T:F-M/M-PEDOT/ZnO/PTB7- Th:O6T-4F:PC71BM/MoO3/Ag
Voc=1.642 V
Jsc=14.35 mA/cm2
FF=73.7%
PCE=17.3%
Fetal Bovine Serum non-USA Origin, Sterile-filtered, Suitable for Cell Culture
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Description
Synonyms: Fetal Calf sera, Fetal Calf serum, FBS, FCS, sera, serum
Fetal calf serum is a common supplement used in cell culture media to promote cell growth and proliferation. It is a non-USA origin fetal calf serum that has been sterile-filtered, making it free from contaminants and suitable for use in cell culture applications. This product is an excellent choice for those looking for a reliable and high-quality fetal calf serum that can support a wide range of cell types in culture.
Formamidinium Iodide | Greatcell Solar® – Sigma Aldrich
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Synonyms
Greatcell Solar®, Iminomethylamine hydriodide, Methanimidamide iodide
General Description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.
Application
Formamidinium iodide (FAI) is an organic halide, which can be used as a precursor solution in the fabrication of perovskite-based heterojunction solar cells.
Formamidinium iodide (FAI) serves as a critical precursor material in the fabrication of perovskite solar cells. FAI is used in material engineering studies to investigate the impact of formamidinium incorporation on perovskite film properties and device performance.
The iodide and bromide based alkylated halides find applications as precursors for fabrication of perovskites for photovoltaic applications.
Legal Information
Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar® is a registered trademark of Greatcell Solar Materials Pty Ltd
Greatcell Solar is a registered trademark of Greatcell Solar
| Description |
Elemental Analysis: C ~7.0% |
| Linear Formula |
CH5IN2 |
| Molecular Weight |
171.97 |
| MDL number |
MFCD28369273 |
| UNSPSC Code |
12352101 |
| NACRES |
Na.23 |
| Greener alternative product characteristics |
Design for Energy Efficiency |
Formamidinium Iodide, ≥99%, Anhydrous – Sigma Aldrich
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Synonyms
Formamidine Hydroiodide, methanimidamide hydroiodide
General Description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.
Application
Formamidinium iodide (FAI) is a compound that finds significant application in the field of photovoltaics, particularly in the development of perovskite solar cells. Formamidinium-based perovskite materials derived from FAI have also shown potential in other optoelectronic applications. These include light-emitting diodes (LEDs), photodetectors and lasers.
Organohalide based perovskites have emerged as an important class of material for solar cell applications[1][2][3][4]. Our perovskites precursors with extremely low water contents are useful for synthesizing mixed cation or anion perovskites needed for the optimization of the band gap, carrier diffusion length and power conversion efficiency of perovskites based solar cells.
| CAS Number |
879643-71-7 |
| Empirical Formula (Hill Notation) |
CH5IN2 |
| Molecular Weight |
171.97 |
| MDL number |
MFCD28369273 |
| UNSPSC Code |
12352111 |
| NACRES |
Na.23 |
| Greener alternative product characteristics |
Design for Energy Efficiency |
Gentamicin sulfate salt – Sigma-Aldrich
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Description
Cas Number : 1045-41-0
Synonyms : Gentiomycin C
Chemical structure: aminoglycoside
Gentamicin, also known as gentiomycin C, is an aminoglycoside, which is naturally produced by Gram-negative bacteria. This antibiotic functions by preventing protein synthesis.[1] Gentamicin sulfate prevents the growth of both Gram positive and Gram negative bacteria, in vivo and in vitro. In tissue culture, gentamicin sulfate is used to inhibit the growth of various strains of mycoplasma.[2].
